Съдържание: Organometallic chemistry ;

Електронна книга

Organometallic chemistry ; Volume 33 /

This Specialist Periodical Report aims to reflect the growing interest in the potential of organometallic chemistry.

Други автори:	Aldridge, S., Boss, Sally., Brennan, J., Butler, I. R., Green, M., Humphrey, M. G., Jelliss, Paul., King, P. J. 1941-, Layfield, Richard A., Linton, David., Lynam, Jason M., Sella, A., Solan, Gregory A., Wheatley, Andrew E. H., Wright, D. S.
Формат:	Електронна книга
Език:	English
Публикувано:	Cambridge : Royal Society of Chemistry, 2007.
Серия:	Specialist periodical report ; v. 33.
Предмети:	Organometallic chemistry. Serials, periodicals, abstracts, indexes. SCIENCE > Chemistry > Organic. Science. Electronic books.
Онлайн достъп:	http://search.ebscohost.com/login.aspx?direct=true&scope=site&db=nlebk&AN=496926

Съдържание:

Groups 1 and 11: The Alkali and Coinage Metals
1 Alkali Metals
1.1 Introduction
1.2 Alkyl Derivatives
1.3 Alkenyl, Allyl, Vinyl, Alkynyl and Related Derivatives
1.4 Aryl Derivatives
1.5 Cyclopentadienyl and Related Derivatives
2 Copper, Silver and Gold
2.1 Introduction
2.2 Copper Compounds
2.3 Silver Compounds
2.4 Gold Compounds
References
Group 2 (Be-Ba) and Group 12 (Zn-Hg)
1 Scope and Organisation of the Review
2 Group 2
3 Group 12
References
Scandium, Yttrium and the Lanthanides
1 Introduction
2 Hydrocarbyls of Various Kinds
3 Half Sandwich Cyclopentadienyl Complexes
4 Metallocene Derivatives
5 Ansa Metallocene Ligand Chemistry
6 Indenyl and Fluorenyl Complexes
7 Functionalized Cyclopentadienyls and Related Ligands
7.1 Functional Groups with Nitrogen Donors
7.2 Functional Groups with Group 16 Donors
8 Hydride Complexes
9 Allyls
10 Cyclo-Octatetraenyl Complexes
11 Nitrogen-Donor Ancillaries
11.1 Ketiminate Chemistry
11.2 Amido Ancillary Groups
12 Organophosphorus Supporting Ligands
13 Aryloxide Ancillaries
14 Compounds with Boron-Based Ligands
15 Materials Chemistry
16 Applications in Organic Synthesis
16.1 Stoichiometric Reactions
16.2 Catalysis
17 Polymerization Catalysis
17.1 Neutral Olefins and Dienes
17.2 Acrylate and Polar Monomer Polymerization
18 Theoretical and Computational Studies
18.1 Structure and Bonding
18.3 Agostic Interactions
18.4 Interaction of Small Molecules
18.5 Calculating Chemical Reactivity
18.6 Pretend Molecules
19 Spectroscopic Studies
References
Carboranes, Including Their Metal Complexes
1 Introduction
2 Theoretical and Computational Studies
3 Heteroboranes, Carboranes and Heterocarboranes
3.1 {B3 and B4}
3.2 {B8, B9 and B10}
3.3 {B12}
3.4 {PCB8}
3.5 {SB8}
3.6 {CB6, CB7, CB8, CB9}
3.7 {CB11}
3.8 {NC2B7}
3.9 {As2C2B7}
3.10 {C2B9}
3.11 {C2B10}
3.12 {C2B11}
4 Metallaboranes and Metallacarboranes
4.1 {MB3 and MB4}
4.2 {MB5}
4.3 {MB6 and MB8}
4.4 {MCB8}
4.5 {MCB9}
4.6 {MCB10}
4.7 {MC2B4}
4.8 {C2B8}
4.9 {MC2B9}
4.10 {MC2B10}
4.11 {MPC2B8}
4.12 {M2C3B8}
4.13 {exo-C2B9}
5 Biological Carborane Chemistry and BNCT
6 Weakly Coordinating Anions and Catalysis
7 Crystal Engineered Supramolecular and Polymeric (Metalla)carborane Materials
References
Group III
B, Al, Ga, In, Tll
1 General
2 Boron
2.1 B(C6F5)3 and Related Boranes
2.2 Borate Anions
2.3 Ligand Systems Based Around a Tri- or Tetra-Coordinate Boron Centre
2.4 Boron Hydrides
2.5 Boron-Based Ligand Systems
2.6 Boratabenzenes and Related Systems
2.7 Boron-Containing Materials and Sensors
2.8 Boronic Acids/Esters and Suzuki Type Coupling Reactions
2.9 Boron Functionalized Cyclopentadienyl Ligands
2.10 Miscellaneous
3 Aluminium
3.1 Hydrides
3.2 Aluminate Complexes
3.3 Aluminium Derivatives Containing Bonds to Group 15 Donors
3.4 Aluminium Derivatives Containing Bonds to Oxygen
3.5 Aluminium Organometallics in Organic Synthesis
3.6 Miscellaneous Examples
4 Gallium
4.1 Subvalent Gallium Species and Clusters
4.2 Complexes Containing Subvalent Gallium Species as Ligands
4.3 Arylgallium Species
4.4 Gallium Hydrides
4.5 Gallium Derivatives Containing Bonds to Group 15 or Group 16 Elements
4.6 Miscellaneous
5 Indium
5.1 Subvalent Indium and Indium Clusters
5.2 Indium Derivatives Containing Bonds to Groups 15 or 16
5.3 Miscellaneous Examples
6 Thallium
References
Group 14: Silicon, Germanium, Tin and Lead
1 Overview
2 Multiple Bonds in Group 14
3 Tetrylenes
4 Radicals, Cations and Anions
5 Homoaromatics and Other Ring Systems
6 Pi-Bonded Complexes
7 Group 14 Organometallics as Ligands at Transition Metal Centres
References
Recent Advances in the Chemistry of Phosphaalkynes: Building Blocks for Novel Organophosphorus Compounds
1 Introduction
2 Synthesis of New Phosphaalkynes
3 Phosphagrignard Reagents and Related Compounds
4 Synthesis of Four-Membered Rings
5 Synthesis of Higher Phosphaalkyne Oligomers
6 Synthesis of Cluster Compounds
7 Conclusions and Outlook
References
Organo-Transition Metal Cluster Complexes
Abbreviations
1 Introduction
2 General Reviews
3 Spectroscopic Studies
4 Theory
5 Structural Studies
6 High-Nuclearity Clusters
6.1 Homonuclear High-Nuclearity Clusters
6.2 Heteronuclear High-Nuclearity Clusters
7 Group 6
8 Group 7
9 Group 8
9.1 Iron
9.2 Ruthenium
9.3 Osmium
9.4 Mixed-Metal Clusters Containing Only Group 8 Metals
9.5 Group 8 Clusters in Catalysis
10 Group 9
10.1 Cobalt
10.2 Rhodium
10.3 Iridium
10.4 Group 9 Mixed-Metal Clusters
11 Group 10
12 Group 11
13 Mixed-Metal Clusters
13.1 Group 5
13.2 Group 6
13.3 Group 7
13.4 Group 8
13.5 Group 9
13.6 Group 10
13.7 Clusters Containing Three Different Metals
References
Complexes Containing Metal-Carbon r-Bonds of the Groups Iron, Cobalt and Nickel, Including Carbenes and Carbynes
1 Introduction
2 Reviews and Articles of General Interest
3 Metal-Carbon s-Bonds Involving Group 8, 9 and 10 Metals
3.1 The Iron Triad
3.2 The Cobalt Triad
3.3 The Nickel Triad
4 Carbene and Carbyne Complexes of Group 8, 9 and 10
References
Organic Aspects of Organometallic Chemistry
1 Introduction
2 Methods for C
C Bond Formation
3 Methods for C
X Bond Formation
4 Metal Mediated Cyclisation and Cycloisomerisation Reactions
5 Nicholas and Pauson-Khand Type Reactions
References

Organometallic chemistry ; Volume 33 /

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